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EUROplast Innovation and Technology Day 2019

The fast eats the slow, desire for innova­tion

On November 18, 2016, a top-class training event took place with the 3rd EUROplast Techno­logy and Innova­tion Day.

The speed at which new products are created is dizzying, but it will never again be as slow as it is today. Product innova­tions must be imple­mented before the compe­ti­tion. Innova­tive products can be sold at high prices; if the product arrives too late, the compe­ti­tion is often already there. We want to look into the future with you, deepen the tried and tested and learn new things.



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Pictures: EUROplast Kunst­stoff­technik GmbH

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EUROplast Innovation and Technology Day 2016

Educa­tion is our greatest raw material in Europe, which is other­wise so resource-poor.

On November 18, 2016, a top-class training event took place with the 2nd EUROplast Innova­tion Day.

Join us on the exciting path to new products: We want to look into the future and will discuss every­thing from the design of material compo­si­tions, plastic-friendly construc­tions, new manufac­tu­ring processes, organic sheets for weight reduc­tion with high strength, CT measu­re­ment and new simula­tion options to innova­tive surface techno­lo­gies . Deepen the tried and tested and experi­ence new things.



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Pictures: EUROplast Kunst­stoff­technik GmbH

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EUROplast “Plastics” issue 07/15

Rotation at maximum speed

Innovative metal replacement with high-precision plastic parts made of PBT/ASA

When desig­ning a new rotating viewing window for deman­ding appli­ca­tions in mecha­nical enginee­ring, an intel­li­gent choice of materials and tool design was required. A tool concept with a tunnel connec­tion and symme­trical sprue distri­butor as well as sophisti­cated tempe­ra­ture control was designed and imple­mented.

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EUROplast in “Basic Report” issue 09/05

Housing for operating table control

In the case Akromid B33 S3 10 natural Magnets are arranged which are used to determine the current position of the operating table.

These magnets are extre­mely sensi­tive to moisture and previously had to be cast into the housing. Europlast EP Kunst­stoff­technik GmbH, Pleidels­heim, imple­mented a signi­fi­cantly cheaper method.
After positio­ning the magnets, the upper and lower housing parts made of impact-resistant modified Akromid B33 S3 10 natural are sealed airtight using sliding friction welding.

Thanks to the blue coloring, the control housing adapts perfectly to the modern appearance of the entire opera­ting equip­ment. The prere­qui­site for the required color unifor­mity is the batch consis­tency of the inherent color of the Akromid B33 S3 10 natural used. The neces­sary impact tests carried out were passed without any restric­tions.

The high dimen­sional stabi­lity of the housing parts is achieved by the Akromid’s low tendency to warp in combi­na­tion with the high level of exper­tise in proces­sing. Compared to impact-modified polyamides from the compe­ti­tion, Akromid B33 S3 10 natural has a good ratio of degas­sing and tool deposit forma­tion. This also leads to quali­ta­tively high-quality molded part surfaces.

Image: EP Kunst­stoff­technik

author

Dipl.-Ing. Elmar Nachts­heim, Managing Director of Europlast, EP Kunst­stoff­technik GmbH, Ilsfeld

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EUROplast in “Plastverarbeiter” issue 06/02

Polyamide for the aviation industry – fire protection in sight

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The problem with components with aviation approval according to ABD and FAR is, on the one hand, the low flammability required, and on the other hand, no toxic fumes must be produced in the event of a fire. A polyamide rises to the challenge.

To date, polycar­bo­nate (PC) has often been used for aviation appli­ca­tions. However, this amorphous material causes problems because of its relatively poor resis­tance to stress cracking. There is a risk that cracks can be triggered by a super­po­si­tion of stresses in conjunc­tion with a chemical attack.

Stresses arise on plastic parts during the manufac­tu­ring process, for example during injec­tion molding or deep drawing — with good workman­ship and a plastic-friendly design of the compon­ents reducing the stress level. Depen­ding on the appli­ca­tion, the compon­ents can also experi­ence considerable stress in the later instal­la­tion situa­tion due to the use of thread-forming screws instead of thread-cutting screws or incor­rectly designed snap hooks.

The compon­ents required are technical functional parts of the seat mecha­nism. When installed, these are exposed to certain stresses and are conta­mi­nated with substances that trigger stress cracks, such as grease, but also food, hand creams or cleaning agents. After every long flight there is a cleaning, which is sometimes carried out in the most remote places in the world. This makes it diffi­cult to specify the substances with which plastic parts may be treated. However, the use of polycar­bo­nate, a material with high impact strength and the possi­bi­lity of flame retar­dancy, poses the risk of stress cracking with almost every commer­ci­ally available cleaning agent.

The property profile of the material that is approved for the aviation industry must meet certain requi­re­ments:

  • Flamma­bi­lity in horizontal test (15s) accor­ding to App.F to part 25 part I § (a),(1),(v)
  • Smoke density per FAR 25.853 (d)
  • Smoke density accor­ding to ABD 0031
  • Toxicity accor­ding to ABD 0031
  • Chemical resis­tance
  • Defined strength and elonga­tion values

After various tests, a dry impact-resistant PA6 GF 15 FR (Foramid GM 96/30–1) was created that was suitable for the aviation industry. The polymer matrix of this material consists of polyamide 6, a semi-crystal­line material with suffi­cient strength and elonga­tion values as well as high chemical resis­tance. To achieve the flame-retar­dant proper­ties, signi­fi­cant amounts of a phosphate- and heavy-metal-free flame retar­dant system were added. Further­more, around 15% glass fiber was compounded to increase strength and rigidity. With a propor­tion of 30%, the material was too brittle due to the high flame retar­dant content. An added rubber-based impact modifier helped to increase the dry impact strength.

Processing aspects

The material can be processed like a normal PA 6 – GF15. To ensure colora­bi­lity, the color must be adjusted exactly to the base material. However, it should be noted that colora­bi­lity is only possible to a limited extent due to the high flame retar­dant content.

The plasti­ci­zing and injec­tion condi­tions must be adjusted so that the blend does not separate. The parame­ters were deter­mined empiri­cally.

Despite the dry impact modifi­ca­tion, the finished injec­tion molded parts should still be condi­tioned with 2–3 % distilled water after comple­tion. This increases the impact strength of the relatively brittle polyamide compound due to the high flame retar­dant content.

The injec­tion mold is equipped with hard inserts made of hot-work steel (1.2344) and has optimal tempe­ra­ture control. Due to the relatively low volumes in the aviation industry, the injec­tion is carried out using a rod and distri­butor without hot runner techno­logy. Care was taken to ensure that the tunnel gate connec­tion was suffi­ci­ently thick. This is important for low shear and suffi­cient pressure supply to the semi-crystal­line material. The weld lines were placed in non-critical areas. Demoul­ding is carried out using flat and round ejectors and, in some cases, using complex slide techno­logy.

Compound production

Due to its versa­ti­lity, the polyamide polymer group has estab­lished itself as one of the most important and versa­tile thermo­pla­s­tics in the field of injec­tion molding granules. The macro­mole­cule is made up of one or two diffe­rent monomers. A distinc­tion is made between PA 6 (but also PA 11 and PA 12) and PA 6.6 (but also PA 4.6 and PA 6.9). The number indicates the number of carbon atoms in the molecule.

The combi­na­tion of halogen- and phosphate-free flame retar­dancy, glass fiber reinforce­ment and impact modifi­ca­tion required for the intended purpose repres­ents a parti­cular chall­enge for the compounder. The aspects of polymer compa­ti­bi­lity, coordi­na­tion of the mecha­nisms of action, safety of the process, environ­mental compa­ti­bi­lity and good econo­mics must be taken into account.

Based on many years of experi­ence, a flame retar­dant system based on melamine cyanurate ( melapur MC 25 from DSM ) proved to be suitable.

It is clear that in PA 6 the end groups NH2 and COOH form a bond with those of MCU, with the forma­tion reaction taking place through opening of the rings and attach­ment. Cyanuric acid is broken down, which at the same time leads to the break­down of Polymaid and thus to a lower smoke gas density. However, it has been shown that the dosage of melamine cyanurate in order to achieve the respec­tive fire class must be set much higher than speci­fied by the manufac­turer.

While 8 weight of % was enough for the MCU 25 product from Chemie Linz in 1992 to achieve V 0 accor­ding to UL 94 (1.6 mm) for unrein­forced PA 6, at least 12.5 weight of % is required with the afore­men­tioned product .

The fire behavior of PA 6 with glass fiber was there­fore only influenced by the flame retar­dant system to the extent that V 2 accor­ding to UL 94 (1.6 mm) was achieved. Since the compon­ents have a wall thick­ness of 3 mm, the flamma­bi­lity drops to V 1 accor­ding to UL 94 and thus meets the flame retar­dancy tests of the aviation industry, which differ from the tests of Under­wri­ters Labora­to­ries.

By adding the impact modifier, in this case an ethylene propy­lene rubber (EPM), to the already high flame retar­dant content, a compli­cated mixture is created that places high demands on the techno­lo­gical process of compoun­ding. Without three gravi­me­tric dosing units on the one hand and the correct choice of visco­sity as a quotient of shear rate and shear stress on the other hand, consis­tent quality cannot be guaran­teed.

Technical functional parts of the seat mecha­nics for the aviation industry
Proces­sing the polyamide on the injec­tion molding machine
Tool techno­logy for produ­cing the functional parts

Images: EP Kunst­stoff­technik

Authors

Dr. Gerhard Pohl, owner of Carl Pohl textile and thermo­pla­stic produc­tion Forst / Lausitz and managing director of Dr. Pohl-Textil- und Thermo­plast GmbH, Forst / Lausitz

Dipl.-Ing. Elmar Nachts­heim, Managing Director of Europlast, EP Kunst­stoff­technik GmbH, Ilsfeld

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EUROplast in plastic processors edition 09/01

Tips for practitioners

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The material matrix is intended to help developers who are not native to the plastics industry narrow down the right material. The matrix is deliberately kept simple, but is intended to help avoid major wrong decisions.

Practice has shown that new develo­p­ments often take wrong paths when it comes to material selec­tion, which are diffi­cult to correct later. If a new product is created, the materials must be largely narrowed down at an early stage of construc­tion, on which, for example, strength calcu­la­tions or shrin­kage are based. Some proper­ties are provided with averaged real values, others only with school grades in order to be able to compare (1: high value / 6: lowest value)

If the raw material price is considered too late because the material was selected based on purely technical aspects, this can endanger an entire project or at least delay it enorm­ously. However, prices are subject to a wide range of fluctua­tions, especi­ally for standard plastics. Shown here is a snapshot of medium quality, with purchase quanti­ties of around 1000 kg (as of September 2001).

In addition to calcu­la­ting its own weight, the density of the material is also included in the calcu­la­tion, since the volume of a plastic part is prede­ter­mined and the weight is only calcu­lated using the specific weight. Here, looking at the volume price is an interes­ting state­ment.

Strength here means the tensile strength, knowing the fact that plastic compon­ents are prima­rily calcu­lated accor­ding to the maximum elonga­tion. This means that you define the environ­mental influences and then look in the tables for the strengths that you can expect the compo­nent to have in order not to exceed the maximum limit elonga­tion.

The level of stress to which a compo­nent is exposed is crucial for its tempe­ra­ture resis­tance. It is also important how long a compo­nent is exposed to high tempe­ra­tures. The values given here are average values of the usage tempe­ra­ture over a medium exposure time and serve as a guide only.

It is important for the designer to know how far the material flows in the mold. Average flow lengths with 2 mm compo­nent thick­nesses are mentioned here. It is important to know that the flow paths increase dispro­por­tio­na­tely with thicker walls. Further­more, in every material group there are also types with better and worse flow proper­ties. And lastly, it must be mentioned that hot runner techno­logy with multiple connec­tions makes it possible to produce parts with a high wall thick­ness-flow path ratio.

For proces­sing shrin­kage during injec­tion molding, only average values are given for a wall thick­ness of 2 — 3 mm and optimal part proces­sing, which are based on years of experi­ence. Due to tool tempe­ra­tures that deviate from the manufacturer’s speci­fi­ca­tions, as well as inade­quate tempe­ra­ture control channels in the tool and extreme cycle times, the real shrin­kage values can deviate signi­fi­cantly from the values stated here. For this reason, the infor­ma­tion provided by raw material manufac­tu­rers often covers a wide range.

The draft angles are important for removing the compon­ents from the mold without drawing marks. Due to the diffe­rent shrin­kage of the materials, the required demoul­ding angles also vary. Further­more, thin walls require larger demol­ding trays than thicker walls. VDI level 30 corre­sponds to a medium struc­ture with a roughing depth of 3.5 μm, although the tool should be designed with VDI level 33 due to the somewhat reduced image.

The average cavity pressure is, on the one hand, a calcu­la­tion variable for the design of the injec­tion molding machine, where strong fluctua­tions can occur depen­ding on the geometry of the compo­nent, and on the other hand, the demol­ding forces also increase as the cavity pressure increases. The number and design of the ejectors must be adapted to these forces.

Impact strength is an important aspect for the suita­bi­lity of plastic compon­ents for everyday use. In addition, the struc­tural design contri­butes signi­fi­cantly to the durabi­lity of a compo­nent after impact stress. The influence of water absorp­tion in polyamide and the general possi­bi­lity of impact modifi­ca­tion with, for example, elastomer modifiers should be mentioned here.

The chemical resis­tance of a plastic is a very complex topic because, in addition to the large number of chemical substances, their concen­tra­tion and the ambient tempe­ra­ture also play a major role. In addition, most common chemi­cals are mixtures of a variety of indivi­dual substances. This means that when asses­sing chemical resis­tance you have to go through long lists of substances and the substances with which the compo­nent later comes into contact are often not tested or these substances are diffi­cult to deter­mine. In general and very simply, one can say: Amorphous plastics (mostly trans­pa­rent plastics, if not colored) have poor chemical resis­tance. Parti­ally crystal­line plastics (mostly opaque plastics, if not colored) have good chemical resis­tance.

Apart from special proces­sing processes (with very fast cooling speeds), all amorphous plastics are more or less trans­pa­rent and all semi-crystal­line plastics are opaque and trans­lu­cent if the wall thick­ness is small. An excep­tion here, however, is ABS, which is opaque although amorphous because it has been copoly­me­rized from diffe­rent raw materials, which influences the refrac­tion of light. Basically, it should be noted that the dimen­sional requi­re­ments are often too high for plastic parts. However, it is often possible to cope with larger tolerances through a plastic-friendly design.

Property matrix of the most common thermoplastics
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EUROplast “Plastics” Issue 10/98

To the point

Optimal sprue position and gate shape for plastic parts

Long-term, often very expen­sive practical experi­ence shows that most errors in tool design are made in the area of injec­tion. Cost-inten­sive correc­tions can be avoided if a design check­list is syste­ma­ti­cally worked through before the tool is designed. The practi­tioner with the relevant profes­sional experi­ence certainly knows and takes into account all the construc­tive aspects mentioned here. Nevert­heless, banal errors still occur in day-to-day business, the number of which can be reduced by consis­t­ently working with the questions compiled here (Table 1). If just one of these questions is answered with “no”, this can lead to subse­quent, expen­sive changes to the tool. The check­list can also be incor­po­rated into a failure mode and effects analysis (FMEA) for tool design. The indivi­dual problems are explained below.

economics

If rework is required to remove the sprue, this must be taken into account when calcu­la­ting the part price. The most common self-separa­ting sprue system with only one parting level that can be operated fully automa­ti­cally is the tunnel sprue. The optimal gate shape with regard to gentle material proces­sing is the bar gate, which, however, is material and post-proces­sing inten­sive and increases manufac­tu­ring costs due to the exten­sion of the cooling time.

Optical aspects

Often the optimal gate location from a technical point of view cannot be realized because the part has to meet deman­ding optical requi­re­ments at this point. In some circum­s­tances, the use of a needle gate nozzle may be considered.

Mold filling

The relati­onship between flow path and wall thick­ness must enable complete mold filling. In addition to complex simula­tion software, the flow curves offered by raw material manufac­tu­rers have proven useful here. These — possibly supple­mented with the graphical filling image method — allow an initial reliable check of the mold filling as long as the geome­tries are relatively simple with uniform wall thick­nesses.

Weld lines

Weld lines should be located in areas of the injec­tion molded part where they cannot lead to strength problems. For complex molded parts, a mold filling study to find the weld seam areas can be worthwhile. A cascade gate system can avoid weld lines, but this signi­fi­cantly increases tooling costs.

Air pockets

It must be ensured that the air in the cavity can escape. We recom­mend air grooves on all ejectors as well as a circum­fe­ren­tial venti­la­tion groove around the entire tool cavity, which is connected to the outside. Ejectors are the best form of venti­la­tion because they clean themselves through their movement. In contrast, sintered inserts or capil­lary inserts have the disad­van­tage that they quickly become clogged due to outgas­sing from the material, thereby affec­ting produc­tion relia­bi­lity.

Free jet bonding

To avoid a free jet, the injec­tion must be carried out against a tool wall and not into the free cavity. This is actually a banal error, but one that is nevert­heless frequently observed (Figure 1). Although the free jet forma­tion can be mitigated by injec­ting with a profile, this modifi­ca­tion of the injec­tion should be reserved for optimi­zing the process and should not be used to conceal tool errors. If neces­sary, the tool must be supple­mented with an auxiliary core in the mold. This may possibly be withdrawn during the reprint phase.

Figure 1: Injec­tion into the free cavity leads to the forma­tion of a free jet instead of a melt front
Shear heating

The shearing of the thermo­pla­stic material during injec­tion must not lead to extreme heating of indivi­dual tool parts. To avoid high tempe­ra­tures, tempe­ra­ture control channels should be provided near the gate. If it is justi­fiable with the tool contour and function, a tempe­ra­ture control hole should be provided with a separate connec­tion opposite the injec­tion point, if possible, so that the shear heat can be speci­fi­cally dissi­pated here. In principle, there must be a tempe­ra­ture control hole in the injec­tion area of hot runner nozzles in order to be able to dissi­pate the inevi­table excess heat from the electri­cally heated nozzle.

Shear stress

The gate geometry (e.g. tunnel gate) must not lead to such a high shear stress that the processed material is damaged. Basically, the bleed should there­fore be made as large as possible. It may also be possible to split a gate into two or more gates to reduce shear. The forma­tion of a weld seam between the cuts must be taken into account. Develo­p­ments in the hot runner sector, especi­ally in extern­ally heated systems, now also allow the proces­sing of relatively tempe­ra­ture-sensi­tive materials. Another option that is still rarely used are liquid-tempered hot runner systems.

Balanced sprue system

For multiple tools or parts with multiple gates, the gating system must of course be balanced. If this is not possible, a mold filling study must be carried out to deter­mine graduated distri­butor cross sections (Figure 2). In general, a naturally balanced sprue system should be used — regard­less of whether it is hot or cold — and only in excep­tional cases should balan­cing be carried out using diffe­ren­tiated distri­butor cross sections, since the visco­sity of the plastic melt depends on the shear that occurs and the tempe­ra­ture. This means that the balan­cing is only exact in one point, namely the calcu­lated point. If the proces­sing parame­ters are subse­quently corrected, a correc­tion of the cross sections is usually also unavo­idable.

Balanced sprue system
Figure 2: If the sprue system is not naturally balanced, atten­tion must be paid to graduated distri­butor cross sections
Hesitation effect

To avoid freezing of the flow front due to the delay effect (hesita­tion effect), the mold must be filled from large wall thick­nesses towards small wall thick­nesses. Thin-walled areas near the gate (e.g. film hinge) should be avoided. The old rule of plastic compo­nent construc­tion of prefer­ring uniform wall thick­nesses is justi­fied here. With diffe­rent wall thick­nesses, the melt only flows along the path of least resis­tance, i.e. in the direc­tion of the greater wall thick­ness. However, the melt then remains on the parts of the smaller wall thick­nesses until suffi­cient pressure has built up. The shear rate approa­ches zero due to the standstill of the mass and the melt front freezes due to its intrinsic visco­sity (Figure 3).

Figure 3: The freezing of the melt due to the hesti­ta­tion effect leads to incom­plete mold filling in the thin-walled area
Reprint

To avoid voids, sink marks, etc., suffi­cient pressure must be ensured. The sprue position should there­fore be chosen so that you are spraying onto a thick wall that is prone to sink marks. Another possi­bi­lity is to intro­duce flow aids between the sprue and mass accumu­la­tions to ensure the supply of additional pressure.

Default

By optimally choosing the sprue position (e.g. injec­tion of a ruler on the narrow side), distor­tion can be largely avoided. Especi­ally with fiber-reinforced materials, but also with semi-crystal­line thermo­pla­s­tics without reinforce­ment, it is important to take the question of poten­tial distor­tion into account when selec­ting the correct injec­tion point. Often several cuts or a film sprue have the effect of reducing distor­tion.

Pictures: Europlast Ep-Kunst­stoff­technik GmbH

author

Dipl.-Ing. Elmar Nachts­heim, born in 1959, worked as a designer at Zeller Plastik KG, Zell/Mosel, after training as a toolmaker. After studying plastics techno­logy at the Darmstadt Univer­sity of Applied Sciences, he was respon­sible for the injec­tion molding techno­logy division at Formplast-Reichel GmbH, Besig­heim. Since 1998 he has been managing director of Europlast Ep-Kunst­stoff­technik GmbH, Ilsfeld.

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EUROplast Innovation and Technology Day 2013

Educa­tion is our greatest raw material in Europe, which is other­wise so resource-poor.

The first EUROplast Innova­tion Day took place on November 8th, 2013.

Join us on the exciting path to new products: from design to material selec­tion — biopo­ly­mers are also presented — to plastic-friendly construc­tion and innova­tive welding techno­logy. Optimized proces­sing methods and cost savings, for example through the use of stack molds, are explained and discussed in greater depth.

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Pictures: EUROplast Kunst­stoff­technik GmbH